Synthesis and characterization of rigid [2.2]paracyclophane-porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes.

Daniel M KnollThomas B WiesnerStefan M MarschnerZahid HassanPatrick WeisManfred KappesMartin NiegerStefan Bräse

Published in: RSC advances (2019)

This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane-porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal-metal fixed-distance Cu/Zn complexes.

Keyphrases

metal organic framework
photodynamic therapy
electron transfer
cancer therapy
heavy metals
tissue engineering
risk assessment
gold nanoparticles