Metal(loid) speciation in a river subjected to industrial anthropopressure: chemometric and environmental studies.

High-performance liquid chromatography (HPLC) coupled with inductively coupled plasma mass spectrometry (ICP-MS) was applied to the speciation of arsenic [As(III), As(V), and AsB (arsenobetaine)], MMA (monomethylarsonic acid), DMA (dimethylarsinic acid), antimony [Sb(III) and Sb(V)], and chromium [Cr(III) and Cr(VI)] in water and bottom sediment samples collected from the urban Bytomka River (Poland). The main objective of the study was the research of As, Cr and Sb species in the Bytomka River, as well as the simplified three-stage sequential chemical extraction of bottom sediments according to the Institute for Reference Materials and Measurements (BCR). The contents of V, Mn, Co, Ni, Cu, Zn, Rb, Sr, Ag, Cd, Te, Ba, Tl, Pb, Fe, Ga, and U in the water and bottom sediments were tested using the ICP-MS technique. The risk assessment code (RAC) indicated a medium risk for As and a high risk for Sb to the environment. Sequential chemical extraction of bottom sediments showed that As and Cr were strongly demobilized. Sb was mainly bound with the ion-exchange fraction and posed a serious threat to the environment. Chemometric analysis with the (dis)similarity analysis and principal component analysis (PCA) allowed for visualization of the variability and correlations of the analyzed elements.