Structure-Property Relationships in Click-Derived Donor-Triazole-Acceptor Materials.
Paul KautnyDorian BaderBerthold StögerGeorg A ReiderJohannes FröhlichDaniel LumpiPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2016)
To shed light on intramolecular charge-transfer phenomena in 1,2,3-triazole-linked materials, a series of 1,2,3-triazole-linked push-pull chromophores were prepared and studied experimentally and computationally. Investigated modifications include variation of donor and/or acceptor strength and linker moiety as well as regioisomers. Photophysical characterization of intramolecular charge-transfer features revealed ambipolar behavior of the triazole linker, depending on the substitution position. Furthermore, non-centrosymmetric materials were subjected to second-harmonic generation measurements, which revealed the high nonlinear optical activity of this class of materials.