Chiral Isolation and Absolute Configuration of (+)- and (-)-Xanchryones F and G from Xanthostemon chrysanthus.

(+)- and (-)-Xanchryones F and G ((+)- and (-)-1 and 2) were isolated from the plant Xanthostemon chrysanthus by chiral separation. Compounds 1 and 2 featured a new carbon skeleton with cinnamoyltriketone-flavone adducts. Their structures with absolute configurations were elucidated by detailed spectroscopic analyses and chemical calculations. The antibacterial and anti-inflammatory activities of (+)- and (-)-1 and 2 were evaluated.