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Magnetic and Electrical Characteristics of Nd 3+ -Doped Lead Molybdato-Tungstate Single Crystals.

Bogdan SawickiElżbieta TomaszewiczTadeusz GrońMonika ObozJoachim KuszMarek Berkowski
Published in: Materials (Basel, Switzerland) (2023)
Single crystals of Pb 1-3 x ▯ x Nd 2 x (MoO 4 ) 1-3 x (WO 4 ) 3 x (PNMWO) with scheelite-type structure, where ▯ denotes cationic vacancies, have been successfully grown by the Czochralski method in air and under 1 MPa. This paper presents the results of structural, optical, magnetic and electrical, as well as the broadband dielectric spectroscopy measurements of PNMWO single crystals. Research has shown that replacing diamagnetic Pb 2+ ions with paramagnetic Nd 3+ ones, with a content not exceeding 0.01 and possessing a screened 4 f -shell, revealed a significant effect of orbital diamagnetism and Van Vleck's paramagnetism, n -type electrical conductivity with an activation energy of 0.7 eV in the intrinsic area, a strong increase of the power factor above room temperature for a crystal with x = 0.005, constant dielectric value (~30) and loss tangent (~0.01) up to room temperature. The Fermi energy (~0.04 eV) and the Fermi temperature (~500 K) determined from the diffusion component of thermopower showed shallow donor levels.
Keyphrases
  • room temperature
  • ionic liquid
  • heavy metals
  • high resolution
  • quantum dots
  • high speed
  • molecularly imprinted
  • single molecule
  • single cell
  • solid state
  • water soluble