Enhancing Proton Co-Intercalation in Iron Ion Batteries Cathodes for Increased Capacity.

Recently, aqueous iron ion batteries (AIIBs) using iron metal anodes have gained traction in the battery community as low-cost and sustainable solutions for green energy storage. However, the development of AIIBs is significantly hindered by the limited capacity of existing cathode materials and the poor intercalation kinetic of Fe 2+ . Herein, we propose a H + and Fe 2+ co-intercalation electrochemistry in AIIBs to boost the capacity and rate capability of cathode materials such as iron hexacyanoferrate (FeHCF) and Na 4 Fe 3 (PO 4 ) 2 (P 2 O 7 ) (NFPP). This is achieved through an electrochemical activation step during which a FeOOH nanowire layer is formed in situ on the cathode. This layer facilitates H + co-intercalation in AIIBs, resulting in a high specific capacity of 151 mAh g -1 and 93% capacity retention over 500 cycles for activated FeHCF cathodes. We found that this activation process can also be applied to other cathode chemistries, such as NFPP, where we found that the cathode capacity is doubled as a result of this process. Overall, the proposed H + /Fe 2+ co-insertion electrochemistry expands the range of applications for AIBBs, in particular as a sustainable solution for storing renewable energy.