Multi-Compartmentalized Cellulose Macrobead Catalysts for In Situ Organic Reaction in Aqueous Media.

This study reports a promising approach to fabricate bacterial cellulose (BC)-based macrobead catalysts with improved catalytic activities and recyclability for organic reactions in aqueous media. To this end, the consecutive extrusion and gelation of BC precursor fluids is conducted using a combined micronozzle device to compartmentalize the resulting BC macrobeads in a programmed manner. The use of BCs laden with Au and Pd nanoparticles (NPs), and Fe 3 O 4 NPs led to the production of catalytically and magnetically compartmentalized BC macrobeads, respectively. Through the model reduction reaction of 4-nitrophenol to 4-aminophenol using NaBH 4 , it is finally demonstrated that the BC macrobead catalysts not only enhance catalytic activities while exhibiting high reaction yields (>99%) in aqueous media, but also repeatedly retrieve the products with ease in response to the applied magnetic field, enabling the establishment of a useful green catalyst platform.