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Interligand C-C Coupling between α-Methyl N-Heterocycles and bipy or phen at Rhenium Tricarbonyl Complexes.

Rebeca ArévaloLucía RieraJulio Pérez
Published in: Inorganic chemistry (2017)
Intramolecular C-C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO)3 fragments. The nucleophilic CH2 group generated by the deprotonation attacks the 6 (bipy) or 2 (phen) positions of the diimines, dearomatizing the involved pyridine ring and generating new asymmetric, fac-capping tridentate ligands.
Keyphrases
  • room temperature
  • ionic liquid
  • energy transfer