Eliminating all bonds from the ground state gives rise to ionic bonding in high-spin states of heterodiatomics.

Understanding chemical bonding in second-row diatomics has been central to elucidating the basics of bonding itself. Bond strength and the number of bonds are the two factors that decide the reactivity of molecules. While bond strengths have been theoretically computed accurately and experimentally determined, the number of bonds is a more contentious issue, especially for complicated multi-reference systems like C 2 . We have developed an experimentally verifiable approach to determine bond numbers from excited spin state potential energy surfaces. On applying this to a series of second-row heterodiatomics, we obtain the surprising phenomenon of an inverted charge transfer ionic state after all the ground state bonds are broken via higher spin states. These ionic states are ubiquitous in all heterodiatomics and unexpected in non-metallic systems.