Self-Suppression of the Giant Coherent Anti-Stokes Raman Scattering Background for Detection of Buried Interfaces with Submonolayer Sensitivity.

Despite its success in many fields, the implementation of coherent anti-Stokes Raman spectroscopy (CARS) in tackling the problems at interfaces was hindered by the enormous resonant and nonresonant background from the bulk. In this work, we have developed a novel CARS scheme that can probe a buried interface via ≥10 5 -fold suppression of the nonresonant and resonant bulk contribution. The method utilizes self-destructive interference between the forward and backward CARS generated in the bulk near the Brewster angle. As a result, we can resolve the vibrational spectrum of submonolayer interfacial polar/apolar species immersed in the surrounding medium with huge CARS responses. We expect that our approach opens up the opportunity to interrogate the interfaces involving apolar molecules and benefits other nonlinear optical spectroscopic techniques, e.g., sum-frequency spectroscopy and four-wave mixing spectroscopy in general, to promote the signal-to-background noise ratio.