An Organic Hybrid Indium-Telluride Incorporating Binuclear Complexes [In2(ea)4]2+ with a Bridging Oxygen Donor.

The new organic hybrid indium-telluride [In2(ea)2Te2]n (1; Hea = ethanolamine) exhibits a new type of one-dimensional polymeric chain based on the linkages of dinuclear [In2(ea)4]2+ and [In2Te4]2- units, which offers the first example of an indium-telluride framework incorporating binuclear complexes [In2(ea)4]2+ with a bridging O donor. 1 shows a distinctive photocurrent response and photocatalytic properties under visible-light illumination.