Mn-Catalysed photoredox hydroxytrifluoromethylation of aliphatic alkenes using CF3SO2Na.

Wenhao LongPengcheng LianJingjing LiXiaobing Wan

Published in: Organic & biomolecular chemistry (2022)

This work demonstrated the photoinduced hydroxytrifluoromethylation of aliphatic alkenes catalysed by Mn(acac)3. The synthesis uses an inexpensive catalyst under mild reaction conditions, and exhibits a wide substrate scope and excellent functional group tolerance.

Keyphrases

room temperature
metal organic framework
visible light
electron transfer
cystic fibrosis
transition metal
ionic liquid
reduced graphene oxide
highly efficient
carbon dioxide
gold nanoparticles
structural basis