Adsorptive Removal of Cd(II) Ions from Water by a Cheap Lignocellulosic Adsorbent and Its Reuse as a Catalyst for the Decontamination of Sulfamethoxazole.

The work reports the removal of cadmium from water by applying an efficient low-cost lignocellulosic adsorbent, rooibos tea waste. The cadmium-loaded rooibos tea waste was used for the photocatalytic abatement of sulfamethoxazole to cater to the setback of secondary pollution mostly associated with the adsorption technique. The rooibos tea waste adsorbent displayed a high removal efficiency of about 90.63% for 10 mg/L Cd(II) ions at 45 °C, 180 min agitation time, pH 7, and a dosage of 500 mg. The process of Cd(II) adsorption was endothermic and spontaneous. Also, the spent adsorbent was found to be efficient toward the photocatalytic breakdown of 10 mg/L sulfamethoxazole with a degradation efficiency of 69% after 150 min. In addition, the extent of mineralization of the sulfamethoxazole by the spent adsorbent as obtained from the total organic carbon data was found to be 53%. Therefore, based on the results obtained from this work, rooibos tea waste lends itself as a cheap, eco-friendly, easily sourced, and viable adsorbent for the removal of toxic ions like Cd(II). Also, the successful reuse of the spent adsorbent is a promising approach to cater to the major setback of secondary pollution associated with adsorption technology.