Hydrophobicity and dielectric properties across an isostructural family of MOFs: a duet or a duel?
Simona SorbaraSoumya MukherjeeAndreas SchneemannRoland A FischerPiero MacchiPublished in: Chemical communications (Cambridge, England) (2022)
An isoreticular family of metal-organic frameworks is post-synthetically subjected to polymer grafting. Surface hydrophobicity analysis, adsorption experiments, and impedance spectroscopy characterise the water molecules adsorbed, both on the surface and in the pores, while resolving how molecular mobility is impacted.