Frenkel-Poole Mechanism Unveils Black Diamond as Quasi-Epsilon-Near-Zero Surface.
Andrea OrsiniDaniele BarettinSara PettinatoStefano SalvatoriRiccardo PoliniMaria Cristina RossiAlessandro BellucciEleonora BolliMarco GirolamiMatteo MastelloneStefano OrlandoValerio SerpenteVeronica ValentiniDaniele Maria TrucchiPublished in: Nanomaterials (Basel, Switzerland) (2023)
A recent innovation in diamond technology has been the development of the "black diamond" (BD), a material with very high optical absorption generated by processing the diamond surface with a femtosecond laser. In this work, we investigate the optical behavior of the BD samples to prove a near to zero dielectric permittivity in the high electric field condition, where the Frenkel-Poole (FP) effect takes place. Zero-epsilon materials (ENZ), which represent a singularity in optical materials, are expected to lead to remarkable developments in the fields of integrated photonic devices and optical interconnections. Such a result opens the route to the development of BD-based, novel, functional photonic devices.