Manipulation of Charge Dynamics for Efficient and Bright Blue Perovskite Light-Emitting Diodes with Chiral Ligands.

Perovskite light-emitting diodes (PeLEDs) emerge as a promising class of optoelectronic devices for next-generation displays and lighting technology. However, the performance of blue PeLEDs lags far behind that of their green and red counterparts, including the unachieved trade-off between high efficiency and high luminance, severe efficiency roll-off, and unsatisfactory power efficiency. Here, a multi-functional chiral ligand of L-phenylalanine methyl ester hydrochloride is strategically introduced into quasi-two-dimensional perovskites, which can effectively passivate defects, modulate the phase distribution, improve photoluminescence quantum yield, guarantee high-quality film morphology, and enhance charge transport. Furthermore, ladder-like hole transport layers are established, boosting charge injection and balance. The resultant sky-blue PeLEDs (the photoluminescence peak is 493 nm, and the electroluminescence peak is 497 nm) exhibit an external quantum efficiency of 12.43% at 1000 cd m -2 and a record power efficiency of 18.42 lm W -1 , rendering that the performance is among the best blue PeLEDs. This article is protected by copyright. All rights reserved.