Rapid Increase in China's Industrial Ammonia Emissions: Evidence from Unit-Based Mapping.

Ammonia (NH 3 ) is an important precursor of secondary inorganic aerosols and greatly impacts nitrogen deposition and acid rain. Previous studies have mainly focused on the agricultural NH 3 emissions, while recent research has noted that industrial sources could be significant in China. However, detailed estimates of NH 3 emitted from industrial sectors in China are lacking. Here, we established an unprecedented high-spatial-resolution data set of China's industrial NH 3 emissions using up-to-date measurements of NH 3 and point source-level information covering eight major industries and 27 subdivided process categories. We found that China emitted 798 (90% confidence interval: 668-933) gigagrams of industrial NH 3 into the atmosphere in 2019, equivalent to 44 ± 20% of the industrial emissions worldwide; this flux is 3-fold larger than that in 1998 and has fluctuated since 2014. Furthermore, although fertilizer production is responsible for approximately half of the emissions in China, the emissions from cement production and coal-fired power plants increased dramatically from near zero to 164 and 41 gigagrams, respectively, in the past two decades, primarily due to the NH 3 escape caused by the large-scale application of the denitration process. Our results reveal that, unlike other major air pollutants, China's industrial NH 3 emission control is still in a critical period, and stricter NH 3 emission standards and innovation in pollution control technologies are highly desirable.