Polydopamine Microsphere-Incorporated Electrospun Fibers as Novel Adsorbents for Dual-Responsive Adsorption of Methylene Blue.

The usually inconvenient detection and uneasy recycling of polydopamine (PDA) with sphere morphology as an adsorbent restrict its actual applications in wastewater purification. Thus, novel composite fibers were fabricated via the electrospinning technique by integrating polydopamine microspheres (PDA-MPs) with pH/temperature dual-responsive copolymers. The insoluble fraction of the fabricated composite fibers can be maintained to a value above 89% after being immersed in aqueous solutions with different pH values. Also, the regeneration efficiency of the composite fibers can also remain above 80% after undergoing five adsorption-desorption cycles. These results both indicated that the fabricated composite fibers can avoid secondary pollution during the adsorption process effectively. In addition, the presence of abundant N-isopropyl acrylamide (NIPAM) units within the fibers could make it have a relatively higher water swelling ability of 4643%, which could further offer relatively larger inner spaces to accommodate the dye molecules. Meanwhile, by incorporating β-cyclodextrin (β-CD), methacrylic acid (MAA), PDA, and NIPAM components, plentiful active adsorption sites could be supplied to interact with methylene blue (MB) dye. So, the adsorption experiments of the composite fibers showed a maximum adsorption capacity of 1722.1 mg/g at pH 9.0 and a temperature of 55 °C. Furthermore, the pseudo-second-order kinetic model of adsorption suggested that it is a chemisorption process. Moreover, the adsorption experimental data can be better described by Langmuir models, inferring its monolayer adsorption. The adsorption thermodynamic studies revealed that adsorption is a spontaneous and endothermic process. Also, the increase of temperature facilitated the adsorption processes, owing to the increase of adsorbent's hydrophobicity and molecules' reactivity. The present work suggested that the combination of smart-responsive polymers and PDA-MPs could form an unprecedented system to be a promising candidate adsorbent for wastewater treatment.