Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex.

Jing XiangJia-Jia LiuXiao-Xiang ChenLi-Hui JiaFei YuBing-Wu WangSong GaoTai-Chu Lau

Published in: Chemical communications (Cambridge, England) (2018)

The synthesis and structure of an 8-coordinate Fe(ii) compound [FeII(L1)2](ClO4)2 (1) with a [FeN4O4] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.

Keyphrases

single molecule
atomic force microscopy
living cells
molecularly imprinted
metal organic framework
high glucose
diabetic rats
endothelial cells
high resolution
solid phase extraction