(Phosphino)(stannyl)carbene.
Rui WeiXin-Feng WangChaopeng HuLiu Leo LiuPublished in: Chemical communications (Cambridge, England) (2024)
The synthesis of a (phosphino)(stannyl)carbene is documented. The combination of phosphino and stannyl substituents imparts a highly ambiphilic nature to this carbene, enabling reactions with cyanide, isocyanide, and carbon monoxide. This leads to rare stannylketenimines and a stannylketene.
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