Effect of the Acid Medium on the Synthesis of Polybenzimidazoles Using Eaton's Reagent.

The influence of trifluoromethanesulfonic (TFSA) superacid on conditions of the synthesis of polybenzimidazoles, such as OPBI and CF 3 PBI, was studied. It was shown that the polycondensations proceeded smoother and at lower temperatures in the presence of the TFSA in Eaton's Reagent and that polymers of high molecular weights, and readily soluble in organic solvents, were obtained. The effect was more pronounced for CF 3 PBI, where the low reactivity monomer, 4,4' (hexafluoroisoproylidene)bis (benzoic acid), was used. CF 3 PBI was obtained at a moderate temperature of 140 °C with no gel fraction and exhibited an inherent viscosity twice higher than the one obtained by the traditional method. In fact, the addition of TFSA allows the obtention of soluble N-phenyl substituted CF 3 PBI by direct synthesis, which had not been obtained otherwise. Thus, the use of TFSA is a good media for the synthesis of N-substituted PBIs under relatively mild conditions.