Advances in Molecular Design and Photophysical Engineering of Perylene Bisimide-Containing Polyads and Multichromophores for Film-Based Fluorescent Sensors.

Film-based fluorescent sensors (FFSs) represent an important chemistry technology for meeting the urgent needs of on-site and real-time analysis, thereby enabling significant applications in environmental and health monitoring. As the core of FFSs, innovative design of sensing fluorophores and their intrinsic excited-state-related response nature endow FFSs with superior sensing performances in an endless expansion. In this Perspective, we specifically focus on perylene bisimide (PBI)-containing polyads and multichromophores with rigid configuration and notable photochemical stability for developing high-performance FFSs. These nonplanar structures mitigate aggregation and create abundant gaps for the sake of mass transfer and availability of the sensing units in the adlayer of the sensing films. We also comprehensively discuss how to adjust electronic coupling governing the excited-state events by appropriate functionalization strategies, thus providing a plethora of valuable insights for the exploration of the structure-property relationships in these orchestrated molecular systems. Throughout this Perspective, we also identify opportunities for FFSs in the future developments.