Differential response for multiple ions: a smart probe to construct optically tunable molecular logic systems.

A rhodamine-based optical probe has been designed through a one-pot synthetic protocol involving phenanthroline as a binding motif. The compound showed a bright pink coloration specifically upon the addition of Cu 2+ and Hg 2+ ions. However, the appearance of bright red fluorescence was observed only in the presence of Hg 2+ . Considering both, we can detect and discriminate these two ions even at ppb level concentration. Furthermore, these in situ generated metal complexes were utilized for the selective recognition of CN - and I - ions. Pre-coated TLC plates were developed for rapid on-site detection of these toxic ions even in remote places. Finally, on a single molecular probe based on differential opto-chemical interactions with different ions (Cu 2+ , Hg 2+ , CN - and I - ), we were able to design numerous trivial (OR, NOR) and non-trivial (INHIBIT, IMPLICATION, COMPLEMENT, TRANSFER, NOT-TRANSFER) logic gates. Most fascinatingly, we can switch the logic response from one type to another by simply tuning only the optical output channel.