Storing electrons from H 2 for transfer to CO 2 , all at room temperature.
Daiki ShimauchiTakeshi YatabeYuka IkesueYuu KajiwaraTaro KoideTatsuya AndoKi-Seok YoonHidetaka NakaiSeiji OgoPublished in: Chemical communications (Cambridge, England) (2023)
We present an Ir complex that extracts electrons from H 2 at room temperature and stores them as a H 2 -derived energy carrier (H 2 EC) at room temperature. Furthermore, we demonstrate that this complex reduces CO 2 to a metal-CO 2 2- species at room temperature, and present the first electrospray ionisation mass spectrum for this compound.