Soft template-assisted copper-doped sodium dititanate nanosheet/graphene oxide heterostructure for photoreduction of carbon dioxide to liquid fuels.

Photoreduction of CO 2 to a high-value product is an interesting approach that not only captures CO 2 but also converts it into other products that can be sold or used in industry. The mechanism for the CO 2 conversion relies strongly on photo-generated electrons that further couple with CO 2 and form active radicals for the reaction. In this research, we synthesized a heterostructure of copper-doped sodium dititanate nanosheets and graphene oxide (CTGN) following a one-step hydrothermal process with assistance from a sodium hydroxide soft template. The role of the template here is to facilitate the formation of the nanosheets, creating the nanosheet-graphene 2D-2D heterostructure. The heterostructure yields excellent charge mobility and a low charge recombination rate, while the nanosheet-graphene interfaces house active radicals and stabilize intermediates. The CTGN exhibits an outstanding photoactivity in the photoreduction of CO 2 , producing liquid fuels, including acetone, methanol, ethanol and i-propanol.