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Crystal structure of methyl (4R)-4-(4-meth-oxy-benzo-yl)-4-{[(1R)-1-phenyl-eth-yl]carbamo-yl}butano-ate.

Alejandro ManchadoMateo M SalgadoÁlvaro VicenteDavid DíezFrancisca SanzNarciso M Garrido
Published in: Acta crystallographica. Section E, Crystallographic communications (2017)
The title compound, C22H25NO5, was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C-N-C(=O)-C torsion angle is 176.1 (6)°. In the crystal, amide-C(4) N-H⋯O and reinforcing C-H⋯O hydrogen bonds link the mol-ecules into infinite [010] chains. Further C-H⋯O hydrogen bonds cross-link the chains in the c-axis direction.
Keyphrases
  • high resolution
  • visible light
  • nitric oxide
  • hydrogen peroxide
  • ionic liquid
  • gram negative
  • solid state