Luminescence switch based on the acid/base induced reversibility of covalent bonds in lanthanide(III) complexes.

We report an exceptional example of Tb(III) luminescence switching using a reversible covalent bond. The antenna and quencher moieties attached to a ligand of a Tb(III) complex undergo acid/base-driven exchange based on the reversible formation of a hemiaminal ether structure to achieve on-off regulation of luminescence.