Hydroxoiridium-Catalyzed Hydroarylation of Alkynes and Bicycloalkenes with N-Sulfonylbenzamides.

Midori NagamotoJun-Ichi FukudaMiyuki HatanoHideki Yorimitsu Takahiro Nishimura

Published in: Organic letters (2018)

Hydroxoiridium complexes efficiently catalyzed the hydroarylation of alkynes and bicycloalkenes with N-sulfonylbenzamides via C-H activation to give the corresponding ortho-alkenylation and alkylation products in high yields.

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