A Brief Discussion of Chemical Kinetics versus Chemical Dynamics.
Patanjali KambhampatiPublished in: The journal of physical chemistry letters (2023)
Chemical kinetics and chemical dynamics are distinct but related topics. They arise again in contemporary physical chemistry often in terms of charge carrier processes in new materials which interconvert light and electrical energy on a distribution of time scales. With this recent rise in the application of concepts in kinetics and dynamics to new problems, there has also arisen confusion about the differences and connections between the two. Here, we briefly review the relationship between kinetics and dynamics in chemical processes, with particular emphasis on the photochemical and photophysical response of a system.