In Operando X-ray Spectroscopic and DFT Studies Revealing Improved H 2 Evolution by the Synergistic Ni-Co Electron Effect in the Alkaline Condition.

The different electrolyte conditions, e.g., pH value, for driving efficient HER and OER are one of the major issues hindering the aim for electrocatalytic water splitting in a high efficiency. In this regard, seeking durable and active HER electrocatalysts to align the alkaline conditions of the OER is a promising solution. However, the success in this strategy will depend on a fundamental understanding about the HER mechanism at the atomic scale. In this work, we have provided thorough understanding for the electrochemical HER mechanisms in KOH over Ni- and Co-based hollow pyrite microspheres by in operando X-ray spectroscopies and DFT calculations, including NiS 2 , CoS 2 , and Ni 0.5 Co 0.5 S 2 . We discovered that the Ni sites in hollow NiS 2 microspheres were very stable and inert, while the Co sites in hollow CoS 2 microspheres underwent reduction and generated Co metallic crystal domains under HER. The generation of Co metallic sites would further deactivate H 2 evolution due to the large hydrogen desorption free energy (-1.73 eV). In contrast, the neighboring Ni and Co sites in hollow Ni 0.5 Co 0.5 S 2 microspheres exhibited the electronic interaction to elevate the reactivity of Ni and facilitate the stability of Co without structure or surface degradation. The energy barrier in H 2 O adsorption/dissociation was only 0.73 eV, followed by 0.06 eV for hydrogen desorption over the Ni 0.5 Co 0.5 S 2 surface, revealing Ni 0.5 Co 0.5 S 2 as a HER electrocatalyst with higher durability and activity than NiS 2 and CoS 2 in the alkaline medium due to the synergy of neighboring Ni and Co sites. We believe that the findings in our work offer a guidance toward future catalyst design.