Functionalized Ordered Mesoporous MCM-48 Silica: Synthesis, Characterization and Adsorbent for CO 2 Capture.

The ordered mesoporous silica MCM-48 with cubic Ia3d structure was synthesized using the cationic surfactant hexadecyltrimethylammonium bromide (CTAB) as a template agent and tetraethylorthosilicate (TEOS) as a silica source. The obtained material was first functionalized with (3-glycidyloxypropyl)trimethoxysilane (KH560); further, two types of amination reagents were used: ethylene diamine (N2) and diethylene triamine (N3). The modified amino-functionalized materials were characterized by powder X-ray diffraction (XRD) at low angles, infrared spectroscopy (FT-IR) and nitrogen adsorption-desorption experiments at 77 K. Characterization from a structural point of view reveals that the ordered MCM-48 mesoporous silica has a highly ordered structure and a large surface area (1466.059 m 2 /g) and pore volume (0.802 cm 3 /g). The amino-functionalized MCM-48 molecular sieves were tested for CO 2 adsorption-desorption properties at different temperatures using thermal program desorption (TPD). Promising results for CO 2 adsorption capacities were achieved for MCM-48 sil KH560-N3 at 30 °C. At 30 °C, the MCM-48 sil KH560-N3 sample has an adsorption capacity of 3.17 mmol CO 2 /g SiO 2 , and an efficiency of amino groups of 0.58 mmol CO 2 /mmolNH 2 . After nine adsorption-desorption cycles, the results suggest that the performance of the MCM-48 sil KH N2 and MCM-48 sil KH N3 adsorbents is relatively stable, presenting a low decrease in the adsorption capacity. The results reported in this paper for the investigated amino-functionalized molecular sieves as absorbents for CO 2 can be considered as promising.