Benzannulation through Ruthenium(0)-Catalyzed Transfer Hydrogenative Cycloaddition: Precision Synthesis and Photophysical Characterization of Soluble Diindenoperylenes.

Sankar Rao SuravarapuSai Prathima ParvathaneniJon A BenderSean T RobertsMichael J Krische

Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)

The first application of ruthenium(0)-catalyzed 1,2-dione-diyne [2+2+2] cycloaddition to PAH construction is achieved by the precision synthesis of soluble diindenoperylenes (DIPs), the electronic structures of which were investigated using steady-state absorption and emission, transient absorption, cyclic voltammetry and time-dependent density functional theory.

Keyphrases

density functional theory
room temperature
molecular dynamics
high resolution
atomic force microscopy
polycyclic aromatic hydrocarbons
single molecule
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high speed