A hexagon based Mn(II) rod metal-organic framework - structure, SF 6 gas sorption, magnetism and electrochemistry.
Francoise M Amombo NoaOcean CheungMichelle ÅhlénElisabet AhlbergPriyanka NehlaGermán Salazar-AlvarezSoheil ErshadradBiplab SanyalLars ÖhrströmPublished in: Chemical communications (Cambridge, England) (2023)
A manganese(II) metal-organic framework based on the hexatopic hexakis(4-carboxyphenyl)benzene, cpb 6- : [Mn 3 (cpb)(dmf) 3 ], was solvothermally prepared showing a Langmuir area of 438 m 2 g -1 , rapid uptake OF sulfur hexafluoride (SF 6 ) as well as electrochemical and magnetic properties, while single crystal diffraction reveals an unusual rod-MOF topology.