Promoting the stability and adsorptive capacity of Fe 3 O 4 -embedded expanded graphite with an aminopropyltriethoxysilane-polydopamine coating for the removal of copper(ii) from water.

In this study, three magnetic graphites, namely, EGF, GAF, and GFA + KH550, were prepared, which were loaded either with Fe 3 O 4 or with Fe 3 O 4 and PDA or with Fe 3 O 4 , PDA, and KH550 onto expanded graphite. ATR-FTIR, XRD, XPS, SEM, TEM, and TGA characterization results showed that EGF, GAF, and GFA + KH550 were successfully prepared. Under the same initial copper concentration, the removal rates of copper ions by EGF, GFA, and GFA + KH550 were 86.2%, 96.9%, and 97.0%, respectively and the hazard index reductions of the three adsorbents were 2191 ± 71 (EGF), 1843 ± 68 (GFA), and 1664 ± 102 (GFA + KH550), respectively. Therefore GFA + KH550 exhibited better removal of Cu(ii) than EGF and GFA, for PDA and KH550 provided more adsorption-active sites like -OH and -NH. Here, the adsorption of GFA + KH550 fitted the pseudo-second-order kinetic and Langmuir models well within the testing range, which means that adsorption occurs on a monolayer surface between Cu(ii) and the adsorption sites. The intraparticle diffusion model and various thermodynamic parameters demonstrated that Cu(ii) was adsorbed on GFA + KH550 mainly via external surface diffusion and that the process was both endothermic and spontaneous. Recycling experiments show that GFA + KH550 has a satisfactory recyclability, and the way of direct recovery by magnets exhibits good magnetic induction. GFA + KH550 was applied in lake water and artificial seawater samples, and exhibited better removal of copper than that in DI water under the same environmental conditions for the existence of macromolecular organic matter. Furthermore, the adsorption capacity of copper ions was not relative to the salinity of water. The application of GFA + KH550 demonstrated the potential for application in water treatment procedures.