Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-Tweezer.

Susana Ibáñez Macarena Poyatos Eduardo Peris

Published in: Angewandte Chemie (International ed. in English) (2017)

A combination of self-complementary π-π-stacking interactions and metallophilic interactions triggered the self-assembly of a new digold(I) metallo-tweezer in the presence of several types of M+ ions. Titrations by fluorescence spectroscopy enabled the determination of the association constants of the resulting inclusion duplex complexes.

Keyphrases

single molecule
gram negative
high resolution
ionic liquid
solid phase extraction
molecularly imprinted
energy transfer
liquid chromatography