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Thermoelectric coupling effect in BNT-BZT-xGaN pyroelectric ceramics for low-grade temperature-driven energy harvesting.

Meng ShenKun LiuGuanghui ZhangQifan LiGuangzu ZhangQingfeng ZhangHaibo ZhangShenglin JiangYong ChenKui Yao
Published in: Nature communications (2023)
Pyroelectric energy harvesting has received increasing attention due to its ability to convert low-grade waste heat into electricity. However, the low output energy density driven by low-grade temperature limits its practical applications. Here, we show a high-performance hybrid BNT-BZT-xGaN thermal energy harvesting system with environmentally friendly lead-free BNT-BZT pyroelectric matrix and high thermal conductivity GaN as dopant. The theoretical analysis of BNT-BZT and BNT-BZT-xGaN with x = 0.1 wt% suggests that the introduction of GaN facilitates the resonance vibration between Ga and Ti, O atoms, which not only contributes to the enhancement of the lattice heat conduction, but also improves the vibration of TiO 6  octahedra, resulting in simultaneous improvement of thermal conductivity and pyroelectric coefficient. Therefore, a thermoelectric coupling enhanced energy harvesting density of 80 μJ cm -3 has been achieved in BNT-BZT-xGaN ceramics with x = 0.1 wt% driven by a temperature variation of 2 o C, at the optical load resistance of 600 MΩ.
Keyphrases
  • low grade
  • high grade
  • energy transfer
  • high frequency
  • heat stress
  • pet ct
  • high resolution
  • heavy metals
  • mass spectrometry
  • ionic liquid