[2.2]Paracyclophane-bridged platinum(II) complexes for silver(I) recognition with emission enhancement.

Yukui Tian Bin ChenSixun JiangMing YuanJie RenFeng Wang

Published in: Chemical communications (Cambridge, England) (2021)

A [2.2]paracyclophane-bridged bimetallic alkynylplatinum(II) terpyridyl complex displays severe emission quenching due to the presence of intramolecular π-π interactions. It undergoes an adaptive conformational change upon recognizing Ag+, which attenuates the intramolecular stacking strength and thereby exhibits "turn-on" emission character.

Keyphrases

energy transfer
molecular dynamics
gold nanoparticles
quantum dots
solid state
early onset
sensitive detection
molecular dynamics simulations
living cells
silver nanoparticles
highly efficient
drug induced