Signatures of Topological Superconductivity in Bulk-Insulating Topological Insulator BiSbTe1.25Se1.75 in Proximity with Superconducting NbSe2.

The combination of superconductivity and spin-momentum locking at the interface between an s-wave superconductor and a three-dimensional topological insulator (3D-TI) is predicted to generate exotic p-wave topological superconducting phases that can host Majorana Fermions. However, large bulk conductivities of previously investigated 3D-TI samples and Fermi level mismatches between 3D bulk superconductors and 2D topological surface states have thwarted significant progress. Here, we employ bulk-insulating topological insulators in proximity with two-dimensional superconductor NbSe2 assembled via van der Waals epitaxy. Experimentally measured differential conductance yields unusual features including a double-gap spectrum, an intrinsic asymmetry that vanishes with small in-plane magnetic fields, and differential conductance ripples at biases significantly larger than the superconducting gap. We explain our results on the basis of proximity-induced superconductivity of topological surface states, while also considering possibilities of topologically trivial superconductivity arising from Rashba-type surface states. Our work demonstrates the possibility of obtaining p-wave superconductors by proximity effects on bulk-insulating TIs.