Hydrogenative depolymerization of silicon-modified polyureas.

Xin LiuYujing ZuoFabian KallmeierEsteban Mejía Sergey Tin Johannes G de Vries Eszter Baráth

Published in: Chemical communications (Cambridge, England) (2022)

Silicon-modified polyureas were depolymerized by hydrogenation in the presence of Ru and Mn catalysts. Yields of up to 84% of the aliphatic diamine and 81% of silicon-containing diamine were achieved with a commercially available PNP-Ru catalyst.

Keyphrases

highly efficient
metal organic framework
room temperature
energy transfer
reduced graphene oxide
carbon dioxide