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Thermal Treatment Impact on the Mechanical Properties of Mg 3 Si 2 O 5 (OH) 4 Nanoscrolls.

Andrei A KrasilinMaksim KhalisovEkaterina KhrapovaValery UgolkovAndrey N EnyashinAlexander Ankudinov
Published in: Materials (Basel, Switzerland) (2022)
A group of phyllosilicate nanoscrolls conjoins several hydrosilicate layered compounds with a size mismatch between octahedral and tetrahedral sheets. Among them, synthetic Mg 3 Si 2 O 5 (OH) 4 chrysotile nanoscrolls (obtained via the hydrothermal method) possess high thermal stability and mechanical properties, making them prospective composite materials fillers. However, accurate determination of these nano-objects with Young's modulus remains challenging. Here, we report on a study of the mechanical properties evolution of individual synthetic phyllosilicate nanoscrolls after a series of heat treatments, observed with an atomic force microscopy and calculated using the density functional theory. It appears that the Young's modulus, as well as shear deformation's contribution to the nanoscrolls mechanical behavior, can be controlled by heat treatment. The main reason for this is the heat-induced formation of covalent bonding between the adjacent layers, which complicate the shear deformation.
Keyphrases
  • density functional theory
  • atomic force microscopy
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