A one-dimensional infinite silver alkynyl assembly [Ag 8 (C[triple bond, length as m-dash]C t Bu) 5 (CF 3 COO) 3 (CH 3 CN)] n : synthesis, crystal structure and properties.
Ju-Feng ShiZhi-Jin ChenLiu-Jie ZhangKun ZhouJiu-Yu JiYan-Feng BiPublished in: RSC advances (2020)
A high-yield silver alkynyl assembly [Ag 8 (C[triple bond, length as m-dash]C t Bu) 5 (CF 3 COO) 3 (CH 3 CN)] n (1) constructed from [AgC[triple bond, length as m-dash]C t Bu] n ligand, CF 3 COOAg and CH 3 CN auxiliary ligands with a one-dimensional infinite chain structure has been obtained in one pot. Compound 1 has been well-defined and characterized. The photocurrent properties and the temperature-sensitive luminescent properties of 1 have been investigated.