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Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes.

Namhyeon KimJung Tae HanDo Hyun RyuJaesook Yun
Published in: Organic letters (2017)
A copper-catalyzed, enantioselective method for the borylallylation of vinyl arenes is reported. The reaction produces enantioenriched and functionalized organoboron compounds by sequentially incorporating boryl and allyl groups onto the C═C bond of vinyl arenes. Copper-catalyzed borylative coupling of vinyl arenes with allyl phosphates successfully proceeds in a regio- and enantioselective manner in the absence of a palladium cocatalyst.
Keyphrases
  • quantum dots
  • gold nanoparticles
  • electron transfer
  • liquid chromatography
  • tandem mass spectrometry