Propargylidyne and Pentadiynylidyne Polyfunctionalised Polycyclic Aromatic Hydrocarbons.
Benjamin J FrogleyAnthony F HillPublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)
The Pd0 /AuI mediated [C1 +C2 ] cross-coupling reactions of [W(≡CBr)(CO)2 (Tp*)] (Tp*=hydrotris(dimethylpyrazolyl)borate) and trimethylsilylethynyl-substituted arenes afford new polycyclic aromatic hydrocarbon propargylidynes [W(≡CC≡CR)(CO)2 (Tp*)] (R=9-anthracenyl, 1-pyrenyl). The strategy extends to the first bis(propargylidyne) and bis(pentadiynylidyne) complexes bridged by phenyl or anthracenyl spacers, and to a tetrakis(propargylidyne) connected through a pyrene core.