Two-Dimensional Functionalized Germananes: Synthesis and Applications.

In the realm of two-dimensional (2D) layered materials, the monoelemental group 14 Xene, germanene, as the germanium analog of graphene, has emerged as the next prospective candidate. Preceded by silicon, germanium is widely used in the semiconductor industry; thus, germanene is deemed compatible with existing semiconductor technologies. Germanene consists of mixed sp 2 -sp 3 -hybridized networks in a buckled hexagonal honeycomb structure. Chemical exfoliation of Zintl phases, such as CaGe 2 , specifically the topotactical deintercalation in acidic media, removes the alkaline earth metal ions Ca 2+ , giving rise to layered germanane (germanene with the Ge centers covalently saturated with terminal hydrogen atoms). Diverse variants of functionalized germananes (with covalent group(s) termination) can be obtained by varying the topotactical deintercalation precursors, elevating the game with limitless functionalization possibilities for customizable properties or new functionalities. We comprehensively cover the preparation of Zintl phases to the details of functionalized and modified germananes and their properties, and the additional exfoliation step to achieve mono- or few-layer germananes. We review the progress and challenges of 2D functionalized germananes in optoelectronics, catalysis, energy conversion and storage, sensors, and biomedical areas. This review provides insight into designing and exploring this class of atomically thin semiconductors in realizing future nanoarchitectonics. This article is protected by copyright. All rights reserved.