Low-resistivity Ohmic contacts of Ti/Al on few-layered 1T'-MoTe 2 /2H-MoTe 2 heterojunctions grown by chemical vapor deposition.

This study explores the phase-controlled growth of few-layered 2H-MoTe 2 , 1T'-MoTe 2 , and 2H-/1T'-MoTe 2 heterostructures and their impacts on metal contact properties. Cold-wall chemical vapor deposition (CW-CVD) with varying growth rates of MoO x and reaction temperatures with Te vapors enabled the growth of continuous thin films of either 1T'-MoTe 2 or 2H-MoTe 2 phases on two-inch sapphire substrates. This methodology facilitates the meticulous optimization of chemical vapor deposition (CVD) parameters, enabling the realization of phase-controlled growth of few-layered MoTe 2 thin films and their subsequent heterostructures. The study further investigates the influence of a 1T'-MoTe 2 intermediate layer on the electrical properties of metal contacts on few-layered 2H-MoTe 2 . Bi-layer Ti/Al contacts directly deposited on 2H-MoTe 2 exhibited Schottky behavior, indicating inefficient carrier transport. However, introducing a few-layered 1T'-MoTe 2 intermediate layer between the metal and 2H-MoTe 2 layers improved the contact characteristics significantly. The resulting Al/Ti/1T'-MoTe 2 /2H-MoTe 2 contact scheme demonstrates Ohmic behavior with a specific contact resistance of around 1.7 × 10 -4 Ω cm 2 . This substantial improvement is attributed to the high carrier concentration of the 1T'-MoTe 2 intermediate layer which could be attributed tentatively to the increased tunneling events across the van der Waals gap and enhancing carrier transport between the metal and 2H-MoTe 2 .