Dielectric, pyroelectric, and ferroelectric studies in (1 - x )AgNbO 3 - x FeNbO 4 lead-free ceramics.

In the present study, the effect of heterovalent Fe 3+ ions on the dielectric, pyroelectric, and ferroelectric properties of the (1 - x )AgNbO 3 - x FeNbO 4 ( x = 0.005, 0.01, 0.025, 0.05, and 0.1) system was investigated. The substitution of smaller ionic radius Fe 3+ in B-sites and the formation of FeNbO 4 as a secondary phase contributed to improved dielectric performance, especially the pyroelectric effect, of (1 - x )AgNbO 3 - x FeNbO 4 ceramics by generating electron-rich ceramics. The (1 - x )AgNbO 3 - x FeNbO 4 ceramics were prepared by conventional solid-state sintering. Pure AgNbO 3 had a perovskite crystal structure with an orthorhombic crystal system, but the FeNbO 4 in (1 - x )AgNbO 3 - x FeNbO 4 ceramics was formed as a secondary phase with a monoclinic structure. In addition, the XRD and Raman spectroscopy data showed that some Fe 3+ was substituted into B-sites of AgNbO 3 . The introduction of FeNbO 4 effectively reduced the average grain size from 1.85 ± 0.09 μm to 1.22 ± 0.03 μm for pure AgNbO 3 and 0.9AgNbO 3 -0.1FeNbO 4 , respectively. In addition, the relative density of the (1 - x )AgNbO 3 - x FeNbO 4 ceramics decreased from 97.96% ± 0.01 for x = 0 to 96.75% ± 0.03 for x = 0.1. The real part of the permittivity ε ', at room temperature, increased from 186.6 for x = 0 to a value of 738.7 for x = 0.1. Additionally, the maximum pyroelectric coefficient increased fivefold, reaching values of 2270 nC cm -2 K -1 for x = 0.1. Furthermore, a harvested pyroelectric energy density ( W ) of 1140 μJ cm -3 for x = 0.025 was achieved, which is appreciably higher than the 840 μJ cm -3 value for x = 0.