Super-Stable, Highly Efficient, and Recyclable Fibrous Metal-Organic Framework Membranes for Precious Metal Recovery from Strong Acidic Solutions.

Precious metals such as palladium (Pd) and platinum (Pt) are marvelous materials in the fields of electronic and catalysis, but they are tapering day by day. Zr(IV)-based metal-organic frameworks (MOFs) are competent for their recovery, notably in harsh environments, while the general powder form limits their practical application. Porous MOF-based membranes with ultraefficient metal ion permeation, strong stability, and high selectivity are, therefore, strikingly preferred. Herein, a set of polymeric fibrous membranes incorporated with the UiO-66 series are fabricated; their adsorption/desorption capabilities toward Pd(II) and Pt(IV) are evaluated from strongly acidic solutions; and the MOF-polymer compatibilities are investigated. Polyurethane (PU)/UiO-66-NH2 showed strong acid resistance and high chemical stability, which are attributable to strong π-π interactions between PU and MOF nanoparticles with a high configuration of energy. The as-fabricated MOF membranes show extremely good adsorption/desorption performances without ruptures/coalitions of nanofibers or leak of MOF nanoparticles, and successfully display the efficacy in a gravity-driven or even continuous-flow system with good recycle performance and selectivity. The as-fabricated MOF membranes set an example of potential MOF-polymer compatibility for practical applications.