Organometallics in molecular junctions: conductance, functions, and reactions.

Molecular junctions, which involve sandwiching molecular structures between electrodes, play a crucial role in molecular electronics. Recent advances in this field have revealed the vital role of organometallic chemistry in the investigation of molecular junctions, which has added to their well-known contributions to catalysis and materials chemistry. This review summarizes the recent examples of organometallic chemistry applications in molecular junctions, which can be categorized into three types, i.e. , class I encompassing molecular junctions with bridging organometallic complexes, class II involving molecular junctions with covalent and noncovalent metal electrode-carbon bonds, and class III comprising organometallic reactions within molecular junctions.