Plasmon-Enhanced Photocatalysis Using Gold Nanoparticles Encapsulated in Nanoscale Molybdenum Oxide Shell.

Using solar energy to enhance the transformation rate of organic molecules is a promising strategy to advance chemical synthesis and environmental remediation. Plasmonic nanoparticles responsive to sunlight show great promise in the catalysis of chemical reactions. In this work, we used a straightforward wet-chemistry method to synthesize plasmonic octahedral gold nanoparticles (NPs) coated with thin molybdenum oxide (MoO3-x), Au@MoO3-x NPs, which exhibited strong surface plasmon resonance in a broad wavelength range. The synthesized Au@MoO3-x NPs were characterized by UV-Vis, SEM, TEM, EDS, XPS, and the electrochemical technique of cyclic voltammetry (CV). The catalytic performance of Au@MoO3-x NPs under visible light irradiation was investigated using the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) as a model reaction. The presence of a thin capping layer of MoO3-x on our Au NPs contributed to the broadening of their range of absorption of visible light, resulting in a stronger intra-particle plasmonic resonance and the modulation of surface energy and electronic state. Accordingly, the kinetics of plasmon photocatalytic transformation of 4-NP to 4-AP was significantly accelerated (by a factor of 8.1) under visible light, compared to uncapped Au NPs in the dark. Our as-synthesized Au@MoO3-x NPs is an example that the range of plasmonic wavelengths of NPs can be effectively broadened by coating them with another plasmon-active (semiconducting) material, which substantially improves their plasmonic photocatalytic performance. Meanwhile, the synthesized Au@MoO3-x NPs can be used to accelerate the transformation of organic molecules under visible light irradiation.