Encapsulation of Cerium Nitrate within Poly(urea-formaldehyde) Microcapsules for the Development of Self-Healing Epoxy-Based Coating.

In order to study the release of cerium nitrate in a self-healing epoxy-based coating, poly (urea-formaldehyde) (PUF) microcapsules containing cerium nitrate were synthesized. The effects of healing agent concentration and weight percent of microcapsules in the epoxy resin were studied through the incorporation of microcapsules within an epoxy-based coating. The prepared microcapsules were characterized using thermogravimetric analysis and Fourier transform infrared spectroscopy and confirmed the successful encapsulation of cerium nitrate within PUF capsules. The self-healing performance of the prepared epoxy coating was investigated in 0.6 M NaCl solution using electrochemical impedance spectroscopy (EIS) tests. The EIS results indicated the successful release of encapsulated cerium nitrate from PUF microcapsules once the damage occurred in the epoxy coating, which led to effective self-healing of the epoxy-based coating. The presence of chlorine and cerium ions in the solution led to the precipitation of cerium hydroxides and oxides in the scratched area as a passive layer which hindered the corrosion in the damaged area. In addition, the EIS results showed that the healing performance of the coatings depends on the weight percent of microcapsules and the concentration of the self-healing agent. The highest self-healing performance was achieved for the maximum amount of microcapsule incorporation (10 wt %), while the increase in the microcapsule percent led to a decrease in the adhesion of the coating to the substrate.